Poly[(μ3-biphenyl-3,4′-dicarboxylato-κ4 O 3:O 3′:O 4′,O 4′′)(1H-imidazo[4,5-f][1,10]phenanthroline-κ2 N 7,N 8)manganese(II)]
نویسنده
چکیده
In the title compound, [Mn(C(14)H(8)O(4))(C(13)H(8)N(4))](n), the Mn(II) atom is six-coordinated in a distorted octa-hedral geometry by four O atoms from three different carboxyl-ate groups and two N atoms from one imidazo[4,5-f][1,10]phenanthroline mol-ecule. The organic ligands link inorganic Mn(II) nodes, forming a zigzag chain along the c axis.
منابع مشابه
Di-μ-sulfato-κ4 O:O′-bis[diaqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ2 N 7,N 9)cobalt(II)] dihydrate
In the centrosymmetric dinuclear title compound, [Co(2)(SO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(4)]·2H(2)O, the Co(II) atom is coord-in-ated by two N atoms from two 1H-imidazo[4,5-f][1,10]phenanthroline ligands, two O atoms from two sulfate anions and two O atoms from water mol-ecules in a distorted octa-hedral geometry. The Co⋯Co separation is 5.1167 (7) Å. The coordinated and uncoordinated water m...
متن کاملBis[[aqua(1H-imidazo[4,5-f][1,10]phenanthroline-κ2 N 6,N 7)cadmium]bis(μ-pyridine-2,3-dicarboxylato)-κ3 N,O 2:O 3;κ3 O 3:N,O 2]
In the title compound, [Cd(2)(C(7)H(3)NO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(2)], the Cd(II) ion is six-coordinated by two N atoms from a 1H-imidazo[4,5-f][1,10]phenanthroline (IP) ligand, one N atom and one O atom from a pyridine-2,3-dicarboxyl-ate (pdc) ligand, one O atom from another pdc ligand and one water mol-ecule in a distorted octa-hedral geometry. Two Cd(II) ions are bridged by a pair of ...
متن کاملcatena-Poly[[diaqua(1H-imidazo[4,5-f][1,10]phenanthroline)cobalt(II)]-μ-sulfato]
The Co(II) ion in the title complex, [Co(SO(4))(C(13)H(8)N(4))(H(2)O)(2)](n), has a slightly distorted octa-hedral coordination environment formed by two O atoms from two symmetry-related bridging sulfate ligands, two N atoms from a bis-chelating 1H-imidazo[4,5-f][1,10]phenanthroline (IPL) ligand and two O atoms from coordinated water mol-ecules. The bridging sulfate ligands connect Co(II) ions...
متن کاملPoly[diaqua(μ4-2,5-dicarboxybenzene-1,4-dicarboxylato-κ4 O 1:O 2:O 4:O 5)(μ2-2,5-dicarboxybenzene-1,4-dicarboxylato-κ2 O 1:O 4)bis(1,10-phenanthroline-κ2 N,N′)dimanganese(II)]
In the title compound, [Mn(2)(C(10)H(4)O(8))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)](n), the Mn(2+) ion has a slightly distorted octa-hedral N(2)O(4) coordination geometry being coordinated by one aqua O atom, two N atoms of the chelating 1,10-phenanthroline ligand and three carboxyl O atoms from three 2,5-dicarb-oxy-benzene-1,4-dicarboxyl-ate (H(2)btec(2-)) ligands. The H(2)btec(2-) anion exhibits two...
متن کاملcatena-Poly[[diaqua(1,10-phenanthroline-κ2 N,N′)nickel(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ2 N 3:O 6]
In the title complex, [Ni(C(9)H(4)N(2)O(4))(C(12)H(8)N(2))(H(2)O)(2)](n), the Ni(II) atom is hexa-coordinated by one N and one O atom from two different 1H-benzimidazole-5,6-dicarboxyl-ate ligands, two N atoms from one 1,10-phenanthroline ligand and two water mol-ecules. The flexible 1H-benzimidazole-5,6-dicarboxyl-ate ligands link the Ni(II) centres, forming an infinite zigzag chain parallel t...
متن کامل